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Issue 44, 2016
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Total synthesis of (±)-ganocins B and C

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Abstract

The first total synthesis of structurally unique polycyclic phenolic meroterpenoids, ganocins B and C is reported. The synthesis features gold-catalyzed intramolecular cascade cyclization to construct the C/D ring bearing an angular methyl group, diastereoselective Michael addition, and acid-mediated one-pot Robinson cyclization/deprotection/isomerization.

Graphical abstract: Total synthesis of (±)-ganocins B and C

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Publication details

The article was received on 19 Sep 2016, accepted on 01 Oct 2016, published on 17 Oct 2016 and first published online on 17 Oct 2016


Article type: Communication
DOI: 10.1039/C6OB02049F
Citation: Org. Biomol. Chem., 2016,14, 10362-10365
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    Total synthesis of (±)-ganocins B and C

    Y. Liu, C. Zhou, Q. Li and H. Wang, Org. Biomol. Chem., 2016, 14, 10362
    DOI: 10.1039/C6OB02049F

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