Issue 36, 2016

DBN hexafluorophosphate salts as convenient sulfonylating and phosphonylating agents

Abstract

Air-stable N-sulfonyl and N-phosphonyl DBN hexafluorophosphate salts have been synthesised under mild conditions as sulfonylating and phosphonylating agents. These salts are highly efficient in the sulfonylation and phosphonylation of a range of N- and O-nucleophiles to generate sulfonamides, sulfonate esters, phosphoramidates and phosphonate esters in good yields.

Graphical abstract: DBN hexafluorophosphate salts as convenient sulfonylating and phosphonylating agents

Supplementary files

Article information

Article type
Communication
Submitted
26 Jul 2016
Accepted
25 Aug 2016
First published
25 Aug 2016

Org. Biomol. Chem., 2016,14, 8452-8456

DBN hexafluorophosphate salts as convenient sulfonylating and phosphonylating agents

C. S. Jones, S. D. Bull and J. M. J. Williams, Org. Biomol. Chem., 2016, 14, 8452 DOI: 10.1039/C6OB01854H

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