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Issue 34, 2016
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Pd-catalyzed cascade allylic alkylation and dearomatization reactions of indoles with vinyloxirane

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Abstract

We have developed Pd-catalyzed intermolecular Friedel–Crafts-type allylic alkylation and allylic dearomatization reactions of substituted indoles bearing a nucleophilic group with vinyloxirane, providing an efficient method to synthesize structurally diverse tetrahydrocarboline and spiroindolenine derivatives under mild conditions.

Graphical abstract: Pd-catalyzed cascade allylic alkylation and dearomatization reactions of indoles with vinyloxirane

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Publication details

The article was received on 18 Jul 2016, accepted on 04 Aug 2016 and first published on 04 Aug 2016


Article type: Communication
DOI: 10.1039/C6OB01523A
Citation: Org. Biomol. Chem., 2016,14, 8044-8046
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    Pd-catalyzed cascade allylic alkylation and dearomatization reactions of indoles with vinyloxirane

    R. Gao, Q. Xu, L. Dai and S. You, Org. Biomol. Chem., 2016, 14, 8044
    DOI: 10.1039/C6OB01523A

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