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Issue 27, 2016
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A prototype reversible polymersome-stabilized H2S photoejector operating under pseudophysiological conditions

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Abstract

Persistent self-assembled polymersome capsules are shown to solubilise and stabilize a new hydrosulfide-containing (2), as well as hydroxylated (1), malachite green derivatives in their leuco-forms in aqueous buffer solution. Photoirradiation resulted in reversible hydroxide release/hydrogen sulfide generation. Notably, the efficient augmentation of H2S concentration to physiologically-relevant levels is shown.

Graphical abstract: A prototype reversible polymersome-stabilized H2S photoejector operating under pseudophysiological conditions

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Publication details

The article was received on 27 May 2016, accepted on 31 May 2016 and first published on 02 Jun 2016


Article type: Communication
DOI: 10.1039/C6OB01155A
Citation: Org. Biomol. Chem., 2016,14, 6394-6397
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    A prototype reversible polymersome-stabilized H2S photoejector operating under pseudophysiological conditions

    A. Tron, A. Peyret, J. Thevenot, R. Bofinger, S. Lecommandoux and N. D. McClenaghan, Org. Biomol. Chem., 2016, 14, 6394
    DOI: 10.1039/C6OB01155A

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