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Issue 16, 2016
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A combined computational and experimental investigation of the oxidative ring-opening of cyclic ethers by oxoammonium cations

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Abstract

The propensity of oxoammonium cations to facilitate the oxidative ring-opening of cyclic ethers to their corresponding distal hydroxy ketones is investigated. The reaction has been evaluated using experimental and computational methods to gain deeper insight into trends in reactivity.

Graphical abstract: A combined computational and experimental investigation of the oxidative ring-opening of cyclic ethers by oxoammonium cations

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Publication details

The article was received on 12 Feb 2016, accepted on 18 Mar 2016 and first published on 18 Mar 2016


Article type: Paper
DOI: 10.1039/C6OB00347H
Citation: Org. Biomol. Chem., 2016,14, 3883-3888
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    A combined computational and experimental investigation of the oxidative ring-opening of cyclic ethers by oxoammonium cations

    Jacob. J. Loman, E. R. Carnaghan, T. A. Hamlin, J. M. Ovian, C. B. Kelly, M. A. Mercadante and N. E. Leadbeater, Org. Biomol. Chem., 2016, 14, 3883
    DOI: 10.1039/C6OB00347H

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