Issue 7, 2016

A metal-free yne-addition/1,4-aryl migration/decarboxylation cascade reaction of alkynoates with Csp3–H centers

Abstract

A metal-free cascade reaction of aryl alkynoates with five different types of radical precursors (R–H) through an yne-addition/1,4-aryl migration/decarboxylation process was reported, which allowed facile and convenient access to functionalized vinyl products with “R” and protons located at the identical carbon of the formed double bond.

Graphical abstract: A metal-free yne-addition/1,4-aryl migration/decarboxylation cascade reaction of alkynoates with Csp3–H centers

Supplementary files

Article information

Article type
Paper
Submitted
04 Dec 2015
Accepted
23 Dec 2015
First published
23 Dec 2015

Org. Biomol. Chem., 2016,14, 2210-2217

Author version available

A metal-free yne-addition/1,4-aryl migration/decarboxylation cascade reaction of alkynoates with Csp3–H centers

D. Kong, L. Cheng, H. Wu, Y. Li, D. Wang and L. Liu, Org. Biomol. Chem., 2016, 14, 2210 DOI: 10.1039/C5OB02478A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements