A versatile synthetic route to prepare alkyl functionalized 3,5-bis-(2-pyridyl)-1,2,4,6-thiatriazines is described that can proceed either via cationic or anionic pathways; confirmed through characterization of the isolable intermediates. Computational studies are presented, which support the regioselectivity of the alkylation reactions and photophysical properties of the S-alkylated derivatives.
E. Kleisath, N. J. Yutronkie, I. Korobkov, B. M. Gabidullin and J. L. Brusso, New J. Chem., 2016, 40, 4472 DOI: 10.1039/C5NJ02611C
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