A novel 2D infinite M3L2 cage-based Cd(II) microporous coordination polymer with a tripodal carboxylic acid ligand and solvent-dependent luminescence properties

Jian Su; Liudi Yao; Jun Zhang; Shizhen Yuan; Fazhi Xie; Yi Ding; Meng Zhao; Shichao Wang; Hao Li; Shengyi Zhang; Jieying Wu; Yupeng Tian

doi:10.1039/C5NJ02144H

A novel 2D infinite M₃L₂ cage-based Cd(ii) microporous coordination polymer with a tripodal carboxylic acid ligand and solvent-dependent luminescence properties†

Jian Su,‡^ab Liudi Yao,‡^ac Jun Zhang,*^ab Shizhen Yuan,^a Fazhi Xie,^a Yi Ding,^a Meng Zhao,^b Shichao Wang,^b Hao Li,^b Shengyi Zhang,^b Jieying Wu^b and Yupeng Tian*^b

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* Corresponding authors

^a Key Laboratory of Functional Molecule Design and Interface Process, Anhui Jianzhu University, Hefei 230601, P. R. China
E-mail: zhangjun@ahjzu.edu.cn

^b Department of Chemistry, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230039, P. R. China
E-mail: yptian@ahu.edu.cn

^c Imperial College London, Department of Medicine, St Mary's Campus, London W21PG, UK

Abstract

A novel M₃L₂ cage-based microporous coordination polymer assembled from the six-coordinated Cd(II) ion and a flexible tricarboxylic ligand has been designed and synthesized. The solvent-dependent luminescence properties revealed that the coordination polymer has an obvious, enhanced luminescence in the solvents CH₂Cl₂ and CHCl₃.

New Journal of Chemistry

A novel 2D infinite M₃L₂ cage-based Cd(ii) microporous coordination polymer with a tripodal carboxylic acid ligand and solvent-dependent luminescence properties†

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A novel 2D infinite M₃L₂ cage-based Cd(II) microporous coordination polymer with a tripodal carboxylic acid ligand and solvent-dependent luminescence properties

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