Issue 22, 2016
From the journal:

Green Chemistry

An unprecedentedly simple method of synthesis of aryl azides and 3-hydroxytriazenes†‡

Pavel S. Gribanov,a   Maxim A. Topchiy,b   Yulia D. Golenko,c   Yana I. Lichtenstein,d   Artur V. Eshtukov,d   Vladimir E. Terekhov,c   Andrey F. Asachenkoa  and  Mikhail S. Nechaev ORCID logo *ac  

* Corresponding authors

a A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky Prospect 29, Moscow, Russia
E-mail: m.nechaev@ips.ac.ru

b A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov Street 28, Moscow 119991, Russia

c Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory 1 (3), Moscow, Russia

d Lomonosov Moscow State University of Fine Chemical Technologies, Vernadskogo Prospect 86, Moscow 119571, Russia

Abstract

Fischer's approach towards the synthesis of aryl azides and triazinoles from diazonium salts and hydroxylammonium chloride (phenylhydraxylamine) was reinvestigated and optimized. The new methodology enables the preparation of aryl azides and triazinoles in high yields in water at room temperature. The procedure is very simple, robust, easily scalable, reproducible, and “green”.

Graphical abstract: An unprecedentedly simple method of synthesis of aryl azides and 3-hydroxytriazenes

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Article information

DOI
https://doi.org/10.1039/C6GC02379G
Article type
Communication
Submitted
25 Aug 2016
Accepted
30 Sep 2016
First published
30 Sep 2016

Green Chem., 2016,18, 5984-5988

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An unprecedentedly simple method of synthesis of aryl azides and 3-hydroxytriazenes

P. S. Gribanov, M. A. Topchiy, Y. D. Golenko, Y. I. Lichtenstein, A. V. Eshtukov, V. E. Terekhov, A. F. Asachenko and M. S. Nechaev, Green Chem., 2016, 18, 5984 DOI: 10.1039/C6GC02379G

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