Issue 46, 2016
From the journal:

Dalton Transactions

Direct synthesis of non-breathing MIL-53(Al)(ht) from a terephthalate-based ionic liquid as linker precursor†

Marcus Fischer,a   Johannes Schwegler,b   Carolin Paula,a   Peter S. Schulz*b  and  Martin Hartmann*a  

* Corresponding authors

a Erlangen Catalysis Resource Center, Friedrich-Alexander Universität Erlangen-Nürnberg, Egerlandstr. 3, 91058 Erlangen, Germany
E-mail: Martin.Hartmann@fau.de
Fax: +49 9131 8567401
Tel: +49 9131 8528792

b Institute of Chemical Reaction Engineering, Friedrich-Alexander Universität Erlangen-Nürnberg, Egerlandstr. 3, 91058 Erlangen, Germany
E-mail: Peter.Schulz@fau.de
Fax: +49 9131 8527421
Tel: +49 9131 8527431

Abstract

An organic imidazolium salt of terephthalic acid has been utilized as a linker precursor for the synthesis of an aluminum-based metal organic framework (MOF) with MIL-53(ht) structure. This material shows the predicted porosity in terms of nitrogen and hydrogen sorption without exhibiting the breathing effect typical for MIL-53(Al) materials.

Graphical abstract: Direct synthesis of non-breathing MIL-53(Al)(ht) from a terephthalate-based ionic liquid as linker precursor

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Article information

DOI
https://doi.org/10.1039/C6DT03930H
Article type
Communication
Submitted
11 Oct 2016
Accepted
21 Oct 2016
First published
25 Oct 2016

Dalton Trans., 2016,45, 18443-18446

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Direct synthesis of non-breathing MIL-53(Al)(ht) from a terephthalate-based ionic liquid as linker precursor

M. Fischer, J. Schwegler, C. Paula, P. S. Schulz and M. Hartmann, Dalton Trans., 2016, 45, 18443 DOI: 10.1039/C6DT03930H

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