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Issue 46, 2016
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Direct synthesis of non-breathing MIL-53(Al)(ht) from a terephthalate-based ionic liquid as linker precursor

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Abstract

An organic imidazolium salt of terephthalic acid has been utilized as a linker precursor for the synthesis of an aluminum-based metal organic framework (MOF) with MIL-53(ht) structure. This material shows the predicted porosity in terms of nitrogen and hydrogen sorption without exhibiting the breathing effect typical for MIL-53(Al) materials.

Graphical abstract: Direct synthesis of non-breathing MIL-53(Al)(ht) from a terephthalate-based ionic liquid as linker precursor

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Publication details

The article was received on 11 Oct 2016, accepted on 21 Oct 2016 and first published on 25 Oct 2016


Article type: Communication
DOI: 10.1039/C6DT03930H
Citation: Dalton Trans., 2016,45, 18443-18446
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    Direct synthesis of non-breathing MIL-53(Al)(ht) from a terephthalate-based ionic liquid as linker precursor

    M. Fischer, J. Schwegler, C. Paula, P. S. Schulz and M. Hartmann, Dalton Trans., 2016, 45, 18443
    DOI: 10.1039/C6DT03930H

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