Issue 41, 2016
From the journal:

Dalton Transactions

Visible-light-induced release of CO by thiolate iron(iii) carbonyl complexes bearing N,C,S-pincer ligands†

Toyotaka Nakae,a   Masakazu Hirotsu,*a   Shigetoshi Aonob  and  Hiroshi Nakajimaa  

* Corresponding authors

a Division of Molecular Materials Science, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan
E-mail: mhiro@sci.osaka-cu.ac.jp

b Okazaki Institute for Integrative Bioscience and Institute for Molecular Science, National Institutes of Natural Sciences, 5-1 Higashiyama, Myodaiji, Okazaki, Aichi 444-8787, Japan

Abstract

Iron(III) carbonyl complexes are stabilized by a pincer ligand containing pyridine-N, phenyl-C and thiolate-S donors and two axial phosphine ligands. The N,C,S-pincer iron(III) carbonyl complexes show CO-releasing properties induced by visible light.

Graphical abstract: Visible-light-induced release of CO by thiolate iron(iii) carbonyl complexes bearing N,C,S-pincer ligands

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Article information

DOI
https://doi.org/10.1039/C6DT03399G
Article type
Communication
Submitted
31 Aug 2016
Accepted
22 Sep 2016
First published
22 Sep 2016

Dalton Trans., 2016,45, 16153-16156

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Visible-light-induced release of CO by thiolate iron(III) carbonyl complexes bearing N,C,S-pincer ligands

T. Nakae, M. Hirotsu, S. Aono and H. Nakajima, Dalton Trans., 2016, 45, 16153 DOI: 10.1039/C6DT03399G

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