Jump to main content
Jump to site search

Issue 41, 2016
Previous Article Next Article

Self-assembly synthesis, structure, topology, and magnetic properties of a mononuclear Fe(III)-violurate derivative: a combined experimental and theoretical study

Author affiliations

Abstract

A new iron(III) complex [Fe(H2Vi)3]·py·4H2O (1) {H3Vi = violuric acid, py = pyridine} was self-assembled and characterized. In the crystal structure, adjacent [Fe(H2Vi)3] blocks are H-bonded into a complex 3D network, which was topologically classified as a pcu [alpha-Po primitive cubic] network. Importance of π-stacking interactions was also highlighted and analyzed computationally. Magnetic studies confirmed antiferromagnetic exchange coupling, while ZFCM/FCM experiments indicated an ordering temperature Tc = 50 K. Finally, magnetic hysteresis at 5 K possesses the coercive field of Bc = 69 mT.

Graphical abstract: Self-assembly synthesis, structure, topology, and magnetic properties of a mononuclear Fe(iii)-violurate derivative: a combined experimental and theoretical study

Back to tab navigation

Supplementary files

Publication details

The article was received on 07 Aug 2016, accepted on 20 Sep 2016 and first published on 20 Sep 2016


Article type: Communication
DOI: 10.1039/C6DT03139K
Citation: Dalton Trans., 2016,45, 16166-16172
  •   Request permissions

    Self-assembly synthesis, structure, topology, and magnetic properties of a mononuclear Fe(III)-violurate derivative: a combined experimental and theoretical study

    R. Banik, S. Roy, Ľ. Dlháň, J. Titiš, R. Boča, A. M. Kirillov, A. D. Martin, A. Bauza, A. Frontera, A. Rodríguez-Diéguez, J. M. Salas and S. Das, Dalton Trans., 2016, 45, 16166
    DOI: 10.1039/C6DT03139K

Search articles by author

Spotlight

Advertisements