A trialuminum-substituted β-isomer Keggin-type tungstoaluminate was synthesized and characterized, in which the pure metal–oxygen cluster [AlW8.5Al0.5{Al(OH2)}3(OH)3O34]6.5− consists of three kinds of aluminum sites: the central Al(1), the doped Al(5), and the substituted Al(2) and Al(3) centers.
Z. Han, H. Zhang, J. Yan and X. Zhai, Dalton Trans., 2016, 45, 14044 DOI: 10.1039/C6DT02618D
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