Issue 36, 2016
From the journal:

Dalton Transactions

Asymmetric dimerization of aniline–ruthenium–dioxolene complex driven by stepwise PCET†

T. Kikuchi,a   K. Kobayashi,a   K. Tsuge,b   S. Kitagawaa  and  K. Tanaka*a  

* Corresponding authors

a Institute for Integrated Cell-Material Sciences, Kyoto University, 105 Jibu-cho, Fushimi-ku, Kyoto 612-8374, ACT Kyoto #507, Japan
E-mail: koji.tanaka@icems.kyoto-u.ac.jp

b Department of Chemistry, Graduate School of Science and Engineering, Toyama University, 3190 Gofuku, Toyama 930-8555, Japan

Abstract

The base-assisted oxidation of an aniline–Ru–quinone complex produced an anilinyl radical–Ru–semiquinone. Furthermore, base-assisted oxidation of the radical complex resulted in selective C–N bond formation through an intermolecular coupling between nitrogen and carbon atoms at the para-position of the anilinyl ligand.

Graphical abstract: Asymmetric dimerization of aniline–ruthenium–dioxolene complex driven by stepwise PCET

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Article information

DOI
https://doi.org/10.1039/C6DT02573K
Article type
Communication
Submitted
28 Jun 2016
Accepted
11 Aug 2016
First published
18 Aug 2016

Dalton Trans., 2016,45, 14030-14034

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Asymmetric dimerization of aniline–ruthenium–dioxolene complex driven by stepwise PCET

T. Kikuchi, K. Kobayashi, K. Tsuge, S. Kitagawa and K. Tanaka, Dalton Trans., 2016, 45, 14030 DOI: 10.1039/C6DT02573K

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