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Issue 35, 2016
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First cage-like pentanuclear Co(II)-silsesquioxane

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Abstract

A new pentanuclear “cylinder”-like cobalt(II) phenylsilsesquioxane [(PhSiO1.5)10(CoO)5(NaOH)] exhibits a slow relaxation of the magnetization and a high catalytic activity and stereoselectivity in the oxidation of alkanes and alcohols.

Graphical abstract: First cage-like pentanuclear Co(ii)-silsesquioxane

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Publication details

The article was received on 20 May 2016, accepted on 08 Jul 2016 and first published on 08 Jul 2016


Article type: Communication
DOI: 10.1039/C6DT02026G
Citation: Dalton Trans., 2016,45, 13663-13666
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    First cage-like pentanuclear Co(II)-silsesquioxane

    A. N. Bilyachenko, A. I. Yalymov, M. M. Levitsky, A. A. Korlyukov, M. A. Es'kova, J. Long, J. Larionova, Y. Guari, L. S. Shul'pina, N. S. Ikonnikov, A. L. Trigub, Y. V. Zubavichus, I. E. Golub, E. S. Shubina and G. B. Shul'pin, Dalton Trans., 2016, 45, 13663
    DOI: 10.1039/C6DT02026G

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