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Issue 27, 2016
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Characterization of Pd⋯H–C interactions in bis-dimethyldithiocarbamate palladium(II) and its deuterated analog by luminescence spectroscopy at variable pressure

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Abstract

We present the variable–pressure d–d luminescence spectra of crystalline bis-dimethyldithiocarbamate palladium(II) and its deuterated analog. The energies and shifts of the band maxima provide evidence for intermolecular Pd⋯H–C interactions, with quantitative differences observed for the deuterated complex. Shifts show distinct interactions in three pressure ranges between 1 bar and 85 kbar.

Graphical abstract: Characterization of Pd⋯H–C interactions in bis-dimethyldithiocarbamate palladium(ii) and its deuterated analog by luminescence spectroscopy at variable pressure

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Publication details

The article was received on 22 Apr 2016, accepted on 13 May 2016 and first published on 13 May 2016


Article type: Communication
DOI: 10.1039/C6DT01574C
Citation: Dalton Trans., 2016,45, 10883-10886
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    Characterization of Pd⋯H–C interactions in bis-dimethyldithiocarbamate palladium(II) and its deuterated analog by luminescence spectroscopy at variable pressure

    S. Poirier, E. Tailleur, H. Lynn and C. Reber, Dalton Trans., 2016, 45, 10883
    DOI: 10.1039/C6DT01574C

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