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Issue 20, 2016
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Does [TcF(CO)5] exist? The crystal and molecular structure of [Tc(CO)3(OH)0.49F0.51]4·[Tc(CO)5(BF4)]

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Abstract

Technetium pentacarbonyl fluoride [TcF(CO)5] was prepared for the first time by reaction of [TcI(CO)5] with solid AgF in a dichloromethane solution at −23 °C. Low temperature crystallization of the resulting compound in a glass vial yielded an unusual complex [Tc(CO)3(OH)0.49F0.51]4·[Tc(CO)5(BF4)] characterized by single crystal XRD.

Graphical abstract: Does [TcF(CO)5] exist? The crystal and molecular structure of [Tc(CO)3(OH)0.49F0.51]4·[Tc(CO)5(BF4)]

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Publication details

The article was received on 10 Mar 2016, accepted on 08 Apr 2016 and first published on 08 Apr 2016


Article type: Paper
DOI: 10.1039/C6DT00958A
Citation: Dalton Trans., 2016,45, 8428-8432
  • Open access: Creative Commons BY license
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    Does [TcF(CO)5] exist? The crystal and molecular structure of [Tc(CO)3(OH)0.49F0.51]4·[Tc(CO)5(BF4)]

    E. S. Stepanova, V. V. Gurzhiy, M. Yu. Tyupina, A. E. Miroslavov, G. V. Sidorenko and A. A. Lumpov, Dalton Trans., 2016, 45, 8428
    DOI: 10.1039/C6DT00958A

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