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Issue 17, 2016
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Redox-mediated reactions of vinylferrocene: toward redox auxiliaries

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Abstract

Chemical redox reactions have been exploited to transform unreactive vinylferrocene into a powerful dienophile for the Diels–Alder reaction and reactive substrate for thiol addition reactions upon conversion to its ferrocenium state. We have further investigated the ability of these reactions to facilitate redox-auxiliary-like reactivity by further hydrogenolyisis of the Diels–Alder adduct to the corresponding cyclopentane derivative.

Graphical abstract: Redox-mediated reactions of vinylferrocene: toward redox auxiliaries

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Publication details

The article was received on 04 Mar 2016, accepted on 29 Mar 2016 and first published on 11 Apr 2016


Article type: Communication
DOI: 10.1039/C6DT00875E
Citation: Dalton Trans., 2016,45, 7220-7225
  • Open access: Creative Commons BY license
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    Redox-mediated reactions of vinylferrocene: toward redox auxiliaries

    A. A. Wiles, X. Zhang, B. Fitzpatrick, D. Long, S. A. Macgregor and G. Cooke, Dalton Trans., 2016, 45, 7220
    DOI: 10.1039/C6DT00875E

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