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Issue 23, 2016
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Bimetallic rare-earth/platinum complexes ligated by phosphinoamides

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Abstract

The heterometallic early-late 5d/4f binuclear phosphinoamido Ln/Pt(0) complexes [(Ph2PNHPh)Pt{μ-(Ph2PNPh)}3Ln(μ-Cl)Li(THF)3] (Ln = Y (1a), Lu (1b)) were obtained by reaction of [Li(THF)4][(Ph2PNPh)4Ln] (Ln = Y, Lu) with the Pt(0) complex [Pt(tBu3P)2] in the presence of LiCl. In the absence of LiCl the corresponding Ln/Pt(0) complexes [(Ph2PNHPh)Pt{μ-(Ph2PNPh)}3Ln{η2-(Ph2PNPh)}][Li(THF)4] (Ln = Y (2a), Lu (2b)) were isolated. Both kind of complexes decompose in solution. The Pt(0) complex [Pt(Ph2PNHPh)4] (3) was identified as one of these decomposition products.

Graphical abstract: Bimetallic rare-earth/platinum complexes ligated by phosphinoamides

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Publication details

The article was received on 29 Jan 2016, accepted on 09 Mar 2016 and first published on 17 Mar 2016


Article type: Paper
DOI: 10.1039/C6DT00417B
Citation: Dalton Trans., 2016,45, 9429-9435
  • Open access: Creative Commons BY license
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    Bimetallic rare-earth/platinum complexes ligated by phosphinoamides

    F. Völcker and P. W. Roesky, Dalton Trans., 2016, 45, 9429
    DOI: 10.1039/C6DT00417B

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