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Issue 15, 2016
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Diphosphane 2,2′-binaphtho[1,8-de][1,3,2]dithiaphosphinine and the easy formation of a stable phosphorus radical cation

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Abstract

A convenient synthesis route to 2,2′-binaphtho[1,8-de][1,3,2]di-thiaphosphinine (3) was found. Its stable radical cation 3˙+ was accessed easily through one-electron oxidation with NOBF4.

Graphical abstract: Diphosphane 2,2′-binaphtho[1,8-de][1,3,2]dithiaphosphinine and the easy formation of a stable phosphorus radical cation

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Publication details

The article was received on 21 Jan 2016, accepted on 11 Mar 2016 and first published on 14 Mar 2016


Article type: Communication
DOI: 10.1039/C6DT00304D
Citation: Dalton Trans., 2016,45, 6348-6351
  • Open access: Creative Commons BY license
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    Diphosphane 2,2′-binaphtho[1,8-de][1,3,2]dithiaphosphinine and the easy formation of a stable phosphorus radical cation

    C. Kirst, B. E. Bode, D. B. Cordes, P. S. Nejman, A. M. Z. Slawin, K. Karaghiosoff and J. D. Woollins, Dalton Trans., 2016, 45, 6348
    DOI: 10.1039/C6DT00304D

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