Issue 15, 2016
From the journal:

Dalton Transactions

Diphosphane 2,2′-binaphtho[1,8-de][1,3,2]dithiaphosphinine and the easy formation of a stable phosphorus radical cation†

Christin Kirst,a   Bela E. Bode,b   David B. Cordes,b   Phillip S. Nejman,b   Alexandra M. Z. Slawin,b   Konstantin Karaghiosoff*a  and  J. Derek Woollins*b  

* Corresponding authors

a Department of Chemistry, Ludwig-Maximilians-University of Munich, Butenandtstr. 5-13 (D), 81377 Munich, Germany
E-mail: konstantin.karaghiosoff@cup.uni-muenchen.de

b EastCHEM School of Chemistry, University of St. Andrews, Fife, UK
E-mail: jdw3@st-andrews.ac.uk

Abstract

A convenient synthesis route to 2,2′-binaphtho[1,8-de][1,3,2]di-thiaphosphinine (3) was found. Its stable radical cation 3˙+ was accessed easily through one-electron oxidation with NOBF4.

Graphical abstract: Diphosphane 2,2′-binaphtho[1,8-de][1,3,2]dithiaphosphinine and the easy formation of a stable phosphorus radical cation

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Article information

DOI
https://doi.org/10.1039/C6DT00304D
Article type
Communication
Submitted
21 Jan 2016
Accepted
11 Mar 2016
First published
14 Mar 2016
This article is Open Access
Creative Commons BY license

Dalton Trans., 2016,45, 6348-6351

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Diphosphane 2,2′-binaphtho[1,8-de][1,3,2]dithiaphosphinine and the easy formation of a stable phosphorus radical cation

C. Kirst, B. E. Bode, D. B. Cordes, P. S. Nejman, A. M. Z. Slawin, K. Karaghiosoff and J. D. Woollins, Dalton Trans., 2016, 45, 6348 DOI: 10.1039/C6DT00304D

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