Issue 9, 2016

Reversible metal-induced emission and chromaticity switching in isostructural Ln-MOFs

Abstract

Several new isostructural lanthanide metal–organic frameworks {[Ln3(L)4(OH)(H2O)2]·DMAC}n (Ln = Tb (1), Gd (2), Eu (3), Gd0.81Tb0.10Eu0.09 (4) and Gd0.75Tb0.18Eu0.07 (5)) were designed and prepared. Excitingly, samples 1, 3, 4 and 5 showed reversible Al3+-induced chromaticity switching as well as reversible Fe3+-induced emission switching.

Graphical abstract: Reversible metal-induced emission and chromaticity switching in isostructural Ln-MOFs

Supplementary files

Article information

Article type
Communication
Submitted
07 Jan 2016
Accepted
28 Jan 2016
First published
08 Feb 2016

Dalton Trans., 2016,45, 3702-3705

Reversible metal-induced emission and chromaticity switching in isostructural Ln-MOFs

Y. Tong, X. Han, C. Huang, Z. Shao, L. Guo, Y. Wang, J. Ding and H. Hou, Dalton Trans., 2016, 45, 3702 DOI: 10.1039/C6DT00067C

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