Issue 7, 2016

Transmetallation from CCC-NHC pincer Zr complexes in the synthesis of air-stable CCC-NHC pincer Co(iii) complexes and initial hydroboration trials

Abstract

Development of CCC-NHC pincer Co complexes via transmetalation from Zr is reported. Formation of these air-stable Co(III) complexes was achieved through use of a CoCl2 or Co(acac)3in situ or with a discrete CCC-NHC pincer Zr transmetallating agent. Preliminary activity in the hydroboration of styrene is reported. This facile methodology will further the development of CCC-NHC pincer first-row transition metal complexes.

Graphical abstract: Transmetallation from CCC-NHC pincer Zr complexes in the synthesis of air-stable CCC-NHC pincer Co(iii) complexes and initial hydroboration trials

Supplementary files

Article information

Article type
Communication
Submitted
04 Dec 2015
Accepted
16 Jan 2016
First published
21 Jan 2016

Dalton Trans., 2016,45, 2823-2828

Author version available

Transmetallation from CCC-NHC pincer Zr complexes in the synthesis of air-stable CCC-NHC pincer Co(III) complexes and initial hydroboration trials

S. W. Reilly, C. E. Webster, T. K. Hollis and H. U. Valle, Dalton Trans., 2016, 45, 2823 DOI: 10.1039/C5DT04752H

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