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Issue 7, 2016
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Transmetallation from CCC-NHC pincer Zr complexes in the synthesis of air-stable CCC-NHC pincer Co(III) complexes and initial hydroboration trials

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Abstract

Development of CCC-NHC pincer Co complexes via transmetalation from Zr is reported. Formation of these air-stable Co(III) complexes was achieved through use of a CoCl2 or Co(acac)3in situ or with a discrete CCC-NHC pincer Zr transmetallating agent. Preliminary activity in the hydroboration of styrene is reported. This facile methodology will further the development of CCC-NHC pincer first-row transition metal complexes.

Graphical abstract: Transmetallation from CCC-NHC pincer Zr complexes in the synthesis of air-stable CCC-NHC pincer Co(iii) complexes and initial hydroboration trials

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Publication details

The article was received on 04 Dec 2015, accepted on 16 Jan 2016 and first published on 21 Jan 2016


Article type: Communication
DOI: 10.1039/C5DT04752H
Citation: Dalton Trans., 2016,45, 2823-2828
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    Transmetallation from CCC-NHC pincer Zr complexes in the synthesis of air-stable CCC-NHC pincer Co(III) complexes and initial hydroboration trials

    S. W. Reilly, C. E. Webster, T. K. Hollis and H. U. Valle, Dalton Trans., 2016, 45, 2823
    DOI: 10.1039/C5DT04752H

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