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Issue 5, 2016
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The design of second generation MOP-phosphonites: efficient chiral hydrosilylation of functionalised styrenes

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Abstract

A series of enantiopure MOP-phosphonite ligands, with tailored steric profiles, have been synthesised and are proven to be very successful in high-yielding, regio- and enantioselective catalytic hydrosilylation reactions of substituted styrenes, affording important chiral secondary alcohols.

Graphical abstract: The design of second generation MOP-phosphonites: efficient chiral hydrosilylation of functionalised styrenes

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Publication details

The article was received on 04 Aug 2015, accepted on 13 Nov 2015 and first published on 25 Nov 2015


Article type: Communication
DOI: 10.1039/C5DT04475H
Citation: Dalton Trans., 2016,45, 1886-1890
  • Open access: Creative Commons BY license
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    The design of second generation MOP-phosphonites: efficient chiral hydrosilylation of functionalised styrenes

    J. T. Fleming, A. Ficks, P. G. Waddell, R. W. Harrington and L. J. Higham, Dalton Trans., 2016, 45, 1886
    DOI: 10.1039/C5DT04475H

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