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Issue 4, 2016
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A designed room-temperature triplet ligand from pyridine-2,6-diyl bis(tert-butyl nitroxide)

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Abstract

The magnetic study on newly developed 4-mesitylpyridine-2,6-diyl bis(tert-butyl nitroxide) shows that almost the whole population has a ground triplet state at room temperature, and the ability of complex formation as a tridentate triplet ligand was proven with a diamagnetic yttrium(III) ion.

Graphical abstract: A designed room-temperature triplet ligand from pyridine-2,6-diyl bis(tert-butyl nitroxide)

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Publication details

The article was received on 27 Oct 2015, accepted on 16 Nov 2015 and first published on 16 Nov 2015


Article type: Communication
DOI: 10.1039/C5DT04218F
Author version available: Download Author version (PDF)
Citation: Dalton Trans., 2016,45, 1306-1309
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    A designed room-temperature triplet ligand from pyridine-2,6-diyl bis(tert-butyl nitroxide)

    H. Kawakami, A. Tonegawa and T. Ishida, Dalton Trans., 2016, 45, 1306
    DOI: 10.1039/C5DT04218F

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