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Issue 2, 2016
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Pd–Co3[Co(CN)6]2 hybrid nanoparticles: preparation, characterization, and challenge for the Suzuki–Miyaura coupling of aryl chlorides under mild conditions

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Abstract

Because of their abundance and low cost, organo chlorides are the most desirable substrates from the industrial point of view in Suzuki–Miyaura cross-coupling reactions. However, catalytic application of Pd nanoparticles (NPs) for Suzuki coupling of aryl chlorides is still a challenge. Here, we design a novel catalyst by combining Pd NPs with Co3[Co(CN)6]2 nanocrystals for Suzuki–Miyaura coupling of aryl chlorides. This nanocatalyst demonstrated good activity (yield 86.2% at 80 °C), high TOF, great stability, easy separation, excellent reusability (initial rates were not reduced after five cycles) and low cost in Suzuki reactions.

Graphical abstract: Pd–Co3[Co(CN)6]2 hybrid nanoparticles: preparation, characterization, and challenge for the Suzuki–Miyaura coupling of aryl chlorides under mild conditions

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Publication details

The article was received on 16 Sep 2015, accepted on 06 Nov 2015 and first published on 11 Nov 2015


Article type: Paper
DOI: 10.1039/C5DT03631C
Author version available: Download Author version (PDF)
Citation: Dalton Trans., 2016,45, 539-544
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    Pd–Co3[Co(CN)6]2 hybrid nanoparticles: preparation, characterization, and challenge for the Suzuki–Miyaura coupling of aryl chlorides under mild conditions

    R. Li, R. Li, C. Wang, L. Gao and Q. Chen, Dalton Trans., 2016, 45, 539
    DOI: 10.1039/C5DT03631C

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