Jump to main content
Jump to site search

Issue 5, 2016
Previous Article Next Article

Synthesis and characterization of manganese triple-decker complexes

Author affiliations

Abstract

The use of the highly sterically demanding CpBIG ligand (CpBIG = C5(4-nBuC6H4)5) and white phosphorus (P4) enables the synthesis of new P-rich derivatives of the rare Pn ligand complexes of manganese. The obtained complexes, [{CpBIGMn}2(μ,η5:5-P5)] (2) and [{CpBIGMn}2(μ,η2:2-P2)2] (3), exhibit the highest number of P atoms in this class of manganese compounds identified by X-ray structure analyses. The EPR spectrum of the 29 VE triple-decker complex 2 shows one unpaired electron coupling with two 5/2 spin Mn nuclei.

Graphical abstract: Synthesis and characterization of manganese triple-decker complexes

Back to tab navigation

Supplementary files

Publication details

The article was received on 08 May 2015, accepted on 02 Jun 2015 and first published on 04 Jun 2015


Article type: Paper
DOI: 10.1039/C5DT01750E
Author version available: Download Author version (PDF)
Citation: Dalton Trans., 2016,45, 1962-1966
  •   Request permissions

    Synthesis and characterization of manganese triple-decker complexes

    S. Heinl, G. Balázs, M. Bodensteiner and M. Scheer, Dalton Trans., 2016, 45, 1962
    DOI: 10.1039/C5DT01750E

Search articles by author

Spotlight

Advertisements