Vibrational dynamics (IR, Raman, NRVS) and a DFT study of a new antitumor tetranuclearstannoxane cluster, Sn(IV)-oxo-{di-o-vanillin} dimethyl dichloride

F. Arjmand; S. Sharma; M. Usman; B. M. Leu; M. Y. Hu; L. Toupet; D. Gosztola; S. Tabassum

doi:10.1039/C6CP02914K

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Vibrational dynamics (IR, Raman, NRVS) and a DFT study of a new antitumor tetranuclearstannoxane cluster, Sn(iv)-oxo-{di-o-vanillin} dimethyl dichloride†

F. Arjmand,*^a S. Sharma,^a M. Usman,^a B. M. Leu,*^b M. Y. Hu,

^b L. Toupet,^c D. Gosztola^d and S. Tabassum^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Aligarh Muslim University, Aligarh 202002, India
E-mail: farukh_arjmand@yahoo.co.in
Tel: +91 5712703893

^b Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, USA
E-mail: leu@aps.anl.gov
Tel: +1 630 252 8821

^c Institut de Physique de Rennes, UMR 625, Université de Rennes 1, Campus de Beaulieu Bat. 11 A, 263 av. Général Leclerc, 35042 Rennes Cedex, France

^d Center for Nanoscale Materials, Argonne National Laboratory, Argonne, Illinois, USA

Abstract

The vibrational dynamics of a newly synthesized tetrastannoxane was characterized with a combination of experimental (Raman, IR and tin-based nuclear resonance vibrational spectroscopy) and computational (DFT/B3LYP) methods, with an emphasis on the vibrations of the tin sites. The cytotoxic activity revealed a significant regression selectively against the human pancreatic cell lines.

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DOI: https://doi.org/10.1039/C6CP02914K
Article type: Communication
Submitted: 30 Apr 2016
Accepted: 08 Jun 2016
First published: 21 Jun 2016

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Phys. Chem. Chem. Phys., 2016,18, 17805-17809

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Vibrational dynamics (IR, Raman, NRVS) and a DFT study of a new antitumor tetranuclearstannoxane cluster, Sn(IV)-oxo-{di-o-vanillin} dimethyl dichloride

F. Arjmand, S. Sharma, M. Usman, B. M. Leu, M. Y. Hu, L. Toupet, D. Gosztola and S. Tabassum, Phys. Chem. Chem. Phys., 2016, 18, 17805 DOI: 10.1039/C6CP02914K

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Physical Chemistry Chemical Physics

Vibrational dynamics (IR, Raman, NRVS) and a DFT study of a new antitumor tetranuclearstannoxane cluster, Sn(iv)-oxo-{di-o-vanillin} dimethyl dichloride†

Abstract

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Vibrational dynamics (IR, Raman, NRVS) and a DFT study of a new antitumor tetranuclearstannoxane cluster, Sn(IV)-oxo-{di-o-vanillin} dimethyl dichloride

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