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Issue 36, 2016
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The 3D [(Cu2Br2){μ-EtS(CH2)4SEt}]n material: a rare example of a coordination polymer exhibiting triplet–triplet annihilation

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Abstract

EtS(CH2)4SEt, L1, forms with CuI a luminescent 2D polymer [Cu4I4{μ-L1}2]n (CP1), which exhibits no triplet excitation energy migration, but with CuBr, it forms a 3D material (CP2), [(Cu2Br2){μ-L1}]n consisting of parallel (Cu2Br2S2)n layers bridged by L1's. CP2 shows T1–T1 annihilation at 298 K but not at 77 K.

Graphical abstract: The 3D [(Cu2Br2){μ-EtS(CH2)4SEt}]n material: a rare example of a coordination polymer exhibiting triplet–triplet annihilation

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The article was received on 07 Jul 2016, accepted on 24 Aug 2016 and first published on 25 Aug 2016


Article type: Communication
DOI: 10.1039/C6CP04728A
Citation: Phys. Chem. Chem. Phys., 2016,18, 24845-24849
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    The 3D [(Cu2Br2){μ-EtS(CH2)4SEt}]n material: a rare example of a coordination polymer exhibiting triplet–triplet annihilation

    A. Bonnot, P. Karsenti, F. Juvenal, C. Golz, C. Strohmann, D. Fortin, M. Knorr and P. D. Harvey, Phys. Chem. Chem. Phys., 2016, 18, 24845
    DOI: 10.1039/C6CP04728A

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