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Issue 38, 2016
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Polymorphism driven optical properties of an anil dye

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Abstract

Red crystals of N,N′-bis(3-methoxysalicylidene)-1,5-diiminonaphthalene were obtained after Schiff base condensation in ethanol. Recrystallization from acetone afforded yellow crystals, a process which is reversible and reproducible. Single crystal X-ray diffraction evidences two polymorphs differing in their space group and dihedral angle between aromatic moieties. DFT periodic calculations further confirmed the existence of two minima on the potential energy surface corresponding to red and yellow crystals. The red polymorph irreversibly (monotropically) transforms at 165–190 °C into the yellow one with a 3% increase of the unit cell volume, as shown by X-ray powder diffraction and periodic DFT calculations. Both polymorphs are thermochromic but only the red one displays photochromism upon irradiation at λ = 365 nm, which is reversible and exhibits a relatively slow thermal relaxation. A temperature induced cis/trans-keto equilibrium is for the first time identified for an N-salicylidene aniline derivative. Static DFT molecular and periodic calculations as well as ab initio Born–Oppenheimer dynamics simulations were performed to characterize the stability of both polymorphs and to determine the relative populations of the enol/cis-keto/trans-keto isomers at various temperatures.

Graphical abstract: Polymorphism driven optical properties of an anil dye

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Publication details

The article was received on 01 Feb 2016, accepted on 01 Mar 2016 and first published on 22 Mar 2016


Article type: Paper
DOI: 10.1039/C6CE00266H
Citation: CrystEngComm, 2016,18, 7249-7259
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    Polymorphism driven optical properties of an anil dye

    D. A. Safin, K. Robeyns, M. G. Babashkina, Y. Filinchuk, A. Rotaru, C. Jureschi, M. P. Mitoraj, J. Hooper, M. Brela and Y. Garcia, CrystEngComm, 2016, 18, 7249
    DOI: 10.1039/C6CE00266H

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