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Issue 22, 2016
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Control of interpenetration of copper-based MOFs on supported surfaces by electrochemical synthesis

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Abstract

A study of a copper-based metal–organic framework (MOF) synthesized by an electrochemical route is presented. Morphological and adsorption properties of the MOF synthesized as bulk powder and on supported copper surfaces were investigated. Differences in these properties and structural refinement studies indicate that when 4,4′,4′′-s-triazine-2,4,6-triyl-tribenzoic acid (H3TATB) is used as linker interpenetration can be prevented when the structure is grown on a surface.

Graphical abstract: Control of interpenetration of copper-based MOFs on supported surfaces by electrochemical synthesis

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Publication details

The article was received on 15 Dec 2015, accepted on 11 Jan 2016 and first published on 11 Jan 2016


Article type: Communication
DOI: 10.1039/C5CE02462E
Citation: CrystEngComm, 2016,18, 4018-4022
  • Open access: Creative Commons BY license
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    Control of interpenetration of copper-based MOFs on supported surfaces by electrochemical synthesis

    S. Sachdeva, A. Pustovarenko, E. J. R. Sudhölter, F. Kapteijn, L. C. P. M. de Smet and J. Gascon, CrystEngComm, 2016, 18, 4018
    DOI: 10.1039/C5CE02462E

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