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Issue 95, 2016
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High performance carbon molecular sieving membranes derived from pyrolysis of metal–organic framework ZIF-108 doped polyimide matrices

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Abstract

Carbon molecular sieve membranes (CMSMs) were fabricated by pyrolysis of MOF-doped polyimide mixed matrix membranes. ZIF-108 (Zn(2-nitroimidazolate)2) was used as a dopant to tailor the micropores of the as-prepared CMSMs into narrow ultramicropores, providing a remarkable combination of permeability and selectivity of membranes in CO2/CH4, O2/N2 and N2/CH4 separation.

Graphical abstract: High performance carbon molecular sieving membranes derived from pyrolysis of metal–organic framework ZIF-108 doped polyimide matrices

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Publication details

The article was received on 27 Sep 2016, accepted on 01 Nov 2016 and first published on 01 Nov 2016


Article type: Communication
DOI: 10.1039/C6CC07833H
Citation: Chem. Commun., 2016,52, 13779-13782
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    High performance carbon molecular sieving membranes derived from pyrolysis of metal–organic framework ZIF-108 doped polyimide matrices

    W. Jiao, Y. Ban, Z. Shi, X. Jiang, Y. Li and W. Yang, Chem. Commun., 2016, 52, 13779
    DOI: 10.1039/C6CC07833H

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