{Tc(NO)(Cp)(PPh3)}+ – a novel technetium(I) core

J. Ackermann; A. Hagenbach; U. Abram

doi:10.1039/C6CC05811F

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

{Tc(NO)(Cp)(PPh₃)}⁺ – a novel technetium(i) core†

J. Ackermann,^a A. Hagenbach^a and U. Abram*^a

Author affiliations

* Corresponding authors

^a Freie Universität Berlin, Institute of Chemistry and Biochemistry, Fabeckstr. 34/36, D-14195 Berlin, Germany
E-mail: Ulrich.Abram@fu-berlin.de

Abstract

Reactions between [Tc^I(NO)X₂(PPh₃)₂(CH₃CN)] complexes (X = Cl, Br) and KCp form the pseudotetrahedral organotechnetium compounds [Tc^I(NO)(Cp)(PPh₃)X]. The halide ligands can readily be replaced by other halides or organometallic ligands giving access to a novel family of technetium(I) compounds with the robust {Tc(NO)(Cp)(PPh₃)}⁺ core.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C6CC05811F
Article type: Communication
Submitted: 14 Jul 2016
Accepted: 22 Jul 2016
First published: 22 Jul 2016
This article is Open Access

Download Citation

Chem. Commun., 2016,52, 10285-10288

Permissions

Request permissions

{Tc(NO)(Cp)(PPh₃)}⁺ – a novel technetium(I) core

J. Ackermann, A. Hagenbach and U. Abram, Chem. Commun., 2016, 52, 10285 DOI: 10.1039/C6CC05811F

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications