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Issue 69, 2016
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Cyclooctyne [60]fullerene hexakis adducts: a globular scaffold for copper-free click chemistry

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Abstract

The synthesis of a new highly symmetric hexakis adduct of C60 appended with 12 cyclooctyne moieties has been carried out. This compound has been used for the copper-free strain-promoted cycloaddition reaction to a series of azides with excellent yields. This strategy for the obtention of clicked adducts of [60]fullerene is of special interest for biological applications.

Graphical abstract: Cyclooctyne [60]fullerene hexakis adducts: a globular scaffold for copper-free click chemistry

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Publication details

The article was received on 01 Jul 2016, accepted on 20 Jul 2016 and first published on 20 Jul 2016


Article type: Communication
DOI: 10.1039/C6CC05484F
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Citation: Chem. Commun., 2016,52, 10544-10546
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    Cyclooctyne [60]fullerene hexakis adducts: a globular scaffold for copper-free click chemistry

    J. Ramos-Soriano, J. J. Reina, A. Pérez-Sánchez, B. M. Illescas, J. Rojo and N. Martín, Chem. Commun., 2016, 52, 10544
    DOI: 10.1039/C6CC05484F

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