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Issue 70, 2016
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From discrete molecule, to polymer, to MOF: mapping the coordination chemistry of CdII using 113Cd solid-state NMR

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Abstract

Studies of three related CdII systems (a discrete [CdII2] unit, a one-dimensional [CdII2]n coordination polymer and a CdII-based MOF) all derived from the ligand 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine, reveal an exceptionally rare example of 113Cd–113Cd J coupling in the polymer that is detectable by solid-state NMR (2JCd–Cd = ∼65 Hz).

Graphical abstract: From discrete molecule, to polymer, to MOF: mapping the coordination chemistry of CdII using 113Cd solid-state NMR

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Publication details

The article was received on 14 Jun 2016, accepted on 02 Aug 2016 and first published on 02 Aug 2016


Article type: Communication
DOI: 10.1039/C6CC04940K
Citation: Chem. Commun., 2016,52, 10680-10683
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    From discrete molecule, to polymer, to MOF: mapping the coordination chemistry of CdII using 113Cd solid-state NMR

    J. M. Frost, L. Kobera, A. Pialat, Y. Zhang, S. A. Southern, B. Gabidullin, D. L. Bryce and M. Murugesu, Chem. Commun., 2016, 52, 10680
    DOI: 10.1039/C6CC04940K

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