Issue 69, 2016

Diaza [1,4] Wittig-type rearrangement of N-allylic-N-Boc-hydrazines into γ-amino-N-Boc-enamines

Abstract

Diaza [1,4] Wittig-type rearrangement of N-allylic-N-Boc-hydrazines into γ-amino-N-Boc-enamines was demonstrated. The scope and limitation, experimental mechanistic studies, and a proposed reaction mechanism were also described.

Graphical abstract: Diaza [1,4] Wittig-type rearrangement of N-allylic-N-Boc-hydrazines into γ-amino-N-Boc-enamines

Supplementary files

Article information

Article type
Communication
Submitted
02 Jun 2016
Accepted
29 Jul 2016
First published
01 Aug 2016

Chem. Commun., 2016,52, 10570-10573

Diaza [1,4] Wittig-type rearrangement of N-allylic-N-Boc-hydrazines into γ-amino-N-Boc-enamines

E. Tayama, Y. Kobayashi and Y. Toma, Chem. Commun., 2016, 52, 10570 DOI: 10.1039/C6CC04626F

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