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Issue 72, 2016
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Synthesis and applications of rhodacyclopentanones derived from C–C bond activation

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Abstract

Rhodacyclopentanones, an “sp3-rich” class of metallacycle, underpin an emerging range of catalytic methodologies for the direct generation of complex scaffolds. This review highlights strategies for accessing rhodacyclopentanones (and related species) by C–C bond activation of cyclobutanones or cyclopropanes. The scope and mechanism of methodologies that exploit these activation modes is outlined.

Graphical abstract: Synthesis and applications of rhodacyclopentanones derived from C–C bond activation

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Publication details

The article was received on 24 May 2016, accepted on 30 Jun 2016 and first published on 07 Jul 2016


Article type: Feature Article
DOI: 10.1039/C6CC04359C
Citation: Chem. Commun., 2016,52, 10817-10829
  • Open access: Creative Commons BY license
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    Synthesis and applications of rhodacyclopentanones derived from C–C bond activation

    M. H. Shaw and J. F. Bower, Chem. Commun., 2016, 52, 10817
    DOI: 10.1039/C6CC04359C

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