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Issue 68, 2016
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Organisation and ordering of 1D porphyrin polymers synthesised by on-surface Glaser coupling

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Abstract

One-dimensional polymer chains consisting of π-conjugated porphyrin units are formed via Glaser coupling on a Ag(111) surface. Scanning probe microscopy reveals the covalent structure of the products and their ordering. The conformational flexibility within the chains is investigated via a comparision of room temperature and cryogenic measurements.

Graphical abstract: Organisation and ordering of 1D porphyrin polymers synthesised by on-surface Glaser coupling

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Publication details

The article was received on 04 May 2016, accepted on 19 Jun 2016 and first published on 20 Jun 2016


Article type: Communication
DOI: 10.1039/C6CC03758E
Citation: Chem. Commun., 2016,52, 10342-10345
  • Open access: Creative Commons BY license
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    Organisation and ordering of 1D porphyrin polymers synthesised by on-surface Glaser coupling

    A. Saywell, A. S. Browning, P. Rahe, H. L. Anderson and P. H. Beton, Chem. Commun., 2016, 52, 10342
    DOI: 10.1039/C6CC03758E

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