Aging of the reaction mixture as a tool to modulate the crystallite size of UiO-66 into the low nanometer range

Marco Taddei; Kim Corinna Dümbgen; Jeroen Anton van Bokhoven; Marco Ranocchiari

doi:10.1039/C6CC02517J

Aging of the reaction mixture as a tool to modulate the crystallite size of UiO-66 into the low nanometer range

Marco Taddei,^a Kim Corinna Dümbgen,^b Jeroen Anton van Bokhoven^a^b and Marco Ranocchiari*^a

Author affiliations

* Corresponding authors

^a Laboratory for Catalysis and Sustainable Chemistry, Paul Scherrer Institute, 5232 Villigen-PSI, Switzerland
E-mail: marco.ranocchiari@psi.ch

^b Institute for Chemical and Bioengineering, ETH Zürich, Vladimir Prelog Weg 1, 8093 Zürich, Switzerland

Abstract

Nanosized UiO-66 with an unprecedented crystallite size of 10 nm was synthesized by exploiting controlled aging of stock solutions of Zr⁴⁺ in N,N-dimethylformamide in the presence of variable amounts of water and acetic acid prior to the addition of the ligand. The yield of the synthesis is not affected, affording high conversion of the starting reagents into the product.

Supplementary files

Publication details

The article was received on 23 Mar 2016, accepted on 10 Apr 2016 and first published on 11 Apr 2016

Article type: Communication

DOI: 10.1039/C6CC02517J

Citation: Chem. Commun., 2016,52, 6411-6414

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Aging of the reaction mixture as a tool to modulate the crystallite size of UiO-66 into the low nanometer range

M. Taddei, K. C. Dümbgen, J. A. van Bokhoven and M. Ranocchiari, Chem. Commun., 2016, 52, 6411
DOI: 10.1039/C6CC02517J
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Chemical Communications

Aging of the reaction mixture as a tool to modulate the crystallite size of UiO-66 into the low nanometer range

Abstract

Supplementary files

Publication details

Aging of the reaction mixture as a tool to modulate the crystallite size of UiO-66 into the low nanometer range

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