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Issue 44, 2016
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Expanding the phosphorus–carbon analogy: formation of an unprecedented 5-phosphasemibullvalene derivative

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Abstract

We could access for the first time a 5-phosphasemibullvalene derivative via quantitative and selective photochemical di-π-methane rearrangement from the corresponding phosphabarrelene. Due to the striking analogy between phosphorus and carbon, this hitherto unknown transformation of vinyl-phosphorus species provides the possibility to prepare novel, chiral and conformationally rigid organophosphorus cage compounds in a straightforward manner.

Graphical abstract: Expanding the phosphorus–carbon analogy: formation of an unprecedented 5-phosphasemibullvalene derivative

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Publication details

The article was received on 21 Mar 2016, accepted on 12 Apr 2016 and first published on 12 Apr 2016


Article type: Communication
DOI: 10.1039/C6CC02461K
Citation: Chem. Commun., 2016,52, 7090-7093
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    Expanding the phosphorus–carbon analogy: formation of an unprecedented 5-phosphasemibullvalene derivative

    M. Rigo, M. Weber and C. Müller, Chem. Commun., 2016, 52, 7090
    DOI: 10.1039/C6CC02461K

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