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Issue 34, 2016
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Efficient multi-click approach to well-defined two-faced octasilsesquioxanes: the first perfect Janus nanocube

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Abstract

The preparation of the first structurally well-defined Janus nanocube showing two chemically distinct opposed faces is described. The synthetic approach is based on a highly efficient and symmetry-controlled CuAAC functionalization of an octa-azido cubic silsesquioxane with a conformationally constrained tetra-alkyne with an appropriate spatial orientation of the triple bonds.

Graphical abstract: Efficient multi-click approach to well-defined two-faced octasilsesquioxanes: the first perfect Janus nanocube

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Publication details

The article was received on 28 Jan 2016, accepted on 01 Mar 2016 and first published on 01 Mar 2016


Article type: Communication
DOI: 10.1039/C6CC00896H
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Citation: Chem. Commun., 2016,52, 5792-5795
  • Open access: Creative Commons BY-NC license
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    Efficient multi-click approach to well-defined two-faced octasilsesquioxanes: the first perfect Janus nanocube

    A. Blázquez-Moraleja, M. Eugenia Pérez-Ojeda, J. R. Suárez, M. Luisa Jimeno and J. L. Chiara, Chem. Commun., 2016, 52, 5792
    DOI: 10.1039/C6CC00896H

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