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Issue 16, 2016
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Sequential Mukaiyama–Michael reaction induced by carbon acids

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Abstract

In the presence of a strong carbon acid, the sequential Mukaiyama–Michael reaction using two different Michael acceptors proceeded and the reaction of ketene silyl acetal derived from EtOAc with α-pyrones as primal acceptors yielded the corresponding cyclic ketene silyl acetals, which were reactive enough to undergo the following reaction with second acceptors.

Graphical abstract: Sequential Mukaiyama–Michael reaction induced by carbon acids

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Publication details

The article was received on 09 Dec 2015, accepted on 21 Dec 2015 and first published on 21 Dec 2015


Article type: Communication
DOI: 10.1039/C5CC10115H
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2016,52, 3280-3283
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    Sequential Mukaiyama–Michael reaction induced by carbon acids

    H. Yanai, O. Kobayashi, K. Takada, T. Isono, T. Satoh and T. Matsumoto, Chem. Commun., 2016, 52, 3280
    DOI: 10.1039/C5CC10115H

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