Issue 12, 2016

Evaluation of iron-based electrocatalysts for water oxidation – an on-line mass spectrometry approach

Abstract

Using on-line mass spectrometry in combination with classical electroanalytical techniques makes it possible to reliably determine onset potentials and to distinguish between competing reactions such as oxygen evolution and carbon dioxide formation. Using these on-line MS methods, catalytic water oxidation activity was demonstrated for cis-[Fe(cyclam)Cl2]Cl (1) and [Fe(cyclamacetate)Cl] (2).

Graphical abstract: Evaluation of iron-based electrocatalysts for water oxidation – an on-line mass spectrometry approach

Supplementary files

Article information

Article type
Communication
Submitted
08 Dec 2015
Accepted
18 Dec 2015
First published
23 Dec 2015

Chem. Commun., 2016,52, 2643-2646

Author version available

Evaluation of iron-based electrocatalysts for water oxidation – an on-line mass spectrometry approach

K. G. Kottrup and D. G. H. Hetterscheid, Chem. Commun., 2016, 52, 2643 DOI: 10.1039/C5CC10092E

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