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Issue 12, 2016
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Evaluation of iron-based electrocatalysts for water oxidation – an on-line mass spectrometry approach

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Abstract

Using on-line mass spectrometry in combination with classical electroanalytical techniques makes it possible to reliably determine onset potentials and to distinguish between competing reactions such as oxygen evolution and carbon dioxide formation. Using these on-line MS methods, catalytic water oxidation activity was demonstrated for cis-[Fe(cyclam)Cl2]Cl (1) and [Fe(cyclamacetate)Cl] (2).

Graphical abstract: Evaluation of iron-based electrocatalysts for water oxidation – an on-line mass spectrometry approach

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The article was received on 08 Dec 2015, accepted on 18 Dec 2015 and first published on 23 Dec 2015


Article type: Communication
DOI: 10.1039/C5CC10092E
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2016,52, 2643-2646
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    Evaluation of iron-based electrocatalysts for water oxidation – an on-line mass spectrometry approach

    K. G. Kottrup and D. G. H. Hetterscheid, Chem. Commun., 2016, 52, 2643
    DOI: 10.1039/C5CC10092E

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