Issue 30, 2016
From the journal:

Chemical Communications

Controlled chiral electrochromism of polyoxometalates incorporated in supramolecular complexes†

Bin Zhang,a   Weiming Guan,a   Simin Zhang,a   Bao Li*a  and  Lixin Wu*a  

* Corresponding authors

a State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130012, China
E-mail: libao@jlu.edu.cn, wulx@jlu.edu.cn

Abstract

A three-component supramolecular system was constructed by combining host–guest recognition and electrostatic interaction for realization of induced circular dichroism of achiral polyanionic clusters in aqueous solution, while the induced chiral heteropoly blue was built and switched off by controlling the redox of the inorganic component via electrochemistry.

Graphical abstract: Controlled chiral electrochromism of polyoxometalates incorporated in supramolecular complexes

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Article information

DOI
https://doi.org/10.1039/C5CC10033J
Article type
Communication
Submitted
06 Dec 2015
Accepted
11 Mar 2016
First published
14 Mar 2016

Chem. Commun., 2016,52, 5308-5311

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Controlled chiral electrochromism of polyoxometalates incorporated in supramolecular complexes

B. Zhang, W. Guan, S. Zhang, B. Li and L. Wu, Chem. Commun., 2016, 52, 5308 DOI: 10.1039/C5CC10033J

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