An original strategy for the synthesis of diblock copolymers where the blocks are linked by a catenane junction is described. Starting from a functionalized catenane precursor, our strategy enables the preparation of a variety of copolymers by different techniques such as ROP, ATRP and CuAAC click reaction.
The article was received on 26 Nov 2015, accepted on 21 Dec 2015 and first published on 21 Dec 2015
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