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Issue 20, 2016
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Neodymium uranyl peroxide synthesis by ion exchange on ammonium uranyl peroxide nanoclusters

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Abstract

This study demonstrates the ability of ammonium uranyl peroxide nanoclusters U32R-NH4 to undergo exchange in between NH4+ and trivalent (Nd3+) or tetravalent (Th4+) cations in the solid state. It paves the way for new promising routes for the synthesis of mixed uranyl peroxides. The exchange ability may also be considered for solution decontamination and synthesis of new mixed actinide-oxide precursors. Both of these applications could be used in the nuclear industry.

Graphical abstract: Neodymium uranyl peroxide synthesis by ion exchange on ammonium uranyl peroxide nanoclusters

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Publication details

The article was received on 17 Nov 2015, accepted on 05 Feb 2016 and first published on 08 Feb 2016


Article type: Communication
DOI: 10.1039/C5CC09527A
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2016,52, 3947-3950
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    Neodymium uranyl peroxide synthesis by ion exchange on ammonium uranyl peroxide nanoclusters

    F. Blanchard, M. Ellart, M. Rivenet, N. Vigier, I. Hablot, B. Morel, S. Grandjean and F. Abraham, Chem. Commun., 2016, 52, 3947
    DOI: 10.1039/C5CC09527A

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