Issue 7, 2016
From the journal:

Analyst

Analytically useful blue chemiluminescence from a water-soluble iridium(iii) complex containing a tetraethylene glycol functionalised triazolylpyridine ligand†

Zoe M. Smith,a   Emily Kerr,a   Egan H. Doeven,b   Timothy U. Connell,ac   Neil W. Barnett,a   Paul S. Donnelly,c   Stephen J. Haswellb  and  Paul S. Francis*a  

* Corresponding authors

a Centre for Chemistry and Biotechnology, School of Life and Environmental Sciences, Deakin University, Locked Bag 20000, Geelong, Victoria 3220, Australia
E-mail: paul.francis@deakin.edu.au

b Centre for Regional and Rural Futures. Deakin University, Locked Bag 20000, Geelong, Victoria 3220, Australia

c School of Chemistry and Bio21 Molecular Science and Biotechnology Institute, University of Melbourne, Melbourne, Victoria 3010, Australia

Abstract

We examine [Ir(df-ppy)2(pt-TEG)]+ as the first highly water soluble, blue-luminescent iridium(III) complex for chemiluminescence detection. Marked differences in selectivity were observed between the new complex and the conventional [Ru(bpy)3]2+ reagent, which will enable this mode of detection to be extended to new areas of application.

Graphical abstract: Analytically useful blue chemiluminescence from a water-soluble iridium(iii) complex containing a tetraethylene glycol functionalised triazolylpyridine ligand

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Article information

DOI
https://doi.org/10.1039/C6AN00141F
Article type
Communication
Submitted
21 Jan 2016
Accepted
22 Feb 2016
First published
26 Feb 2016
This article is Open Access
Creative Commons BY-NC license

Analyst, 2016,141, 2140-2144

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Analytically useful blue chemiluminescence from a water-soluble iridium(III) complex containing a tetraethylene glycol functionalised triazolylpyridine ligand

Z. M. Smith, E. Kerr, E. H. Doeven, T. U. Connell, N. W. Barnett, P. S. Donnelly, S. J. Haswell and P. S. Francis, Analyst, 2016, 141, 2140 DOI: 10.1039/C6AN00141F

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