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Issue 47, 2015
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The electronic structure of sulvanite structured semiconductors Cu3MCh4 (M = V, Nb, Ta; Ch = S, Se, Te): prospects for optoelectronic applications

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Abstract

The electronic structure of a family of ternary copper chalcogenide systems Cu3MCh4 (M = V, Nb, Ta; Ch = S, Se, Te) has been explored to ascertain the compounds' potential for optoelectronic device applications. The lattice parameters, density of states, band gap, optical absorption, and effective mass of each of the nine systems were determined with PBEsol+U, and a valence band alignment was performed to assess the doping limits of the series. The calculated optical band gaps of the materials range from 1.19 eV for Cu3VTe4 to 2.60 eV for Cu3TaS4, with the former also predicted to have the highest valence band maximum and the lowest hole effective mass of the series, indicative of a p-type material with photovoltaic potential. The wide range of band gap energies predicted in this series of isostructural materials evidences how selective combination of elements in ternary systems can be used to tune electronic properties through alloying and thus target ideal values for specific applications. Five materials in the series are predicted to have optical band gaps suitable for solar cell absorbers, with Cu3NbTe4 and Cu3TaTe4 being of particular interest due not only to their respective band gaps of 1.46 eV and 1.69 eV but also their potential to be alloyed based on their similar lattice constants and valence band energies.

Graphical abstract: The electronic structure of sulvanite structured semiconductors Cu3MCh4 (M = V, Nb, Ta; Ch = S, Se, Te): prospects for optoelectronic applications

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Publication details

The article was received on 03 Sep 2015, accepted on 03 Nov 2015 and first published on 04 Nov 2015


Article type: Paper
DOI: 10.1039/C5TC02760H
Citation: J. Mater. Chem. C, 2015,3, 12236-12244
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    The electronic structure of sulvanite structured semiconductors Cu3MCh4 (M = V, Nb, Ta; Ch = S, Se, Te): prospects for optoelectronic applications

    A. B. Kehoe, D. O. Scanlon and G. W. Watson, J. Mater. Chem. C, 2015, 3, 12236
    DOI: 10.1039/C5TC02760H

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