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Issue 21, 2015
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Radiative and non-radiative decay rate of K2SiF6:Mn4+ phosphors

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Abstract

Mn4+-activated K2SiF6 phosphors for use in light emitting diode (LED) applications have recently attracted a great deal of attention since they exhibit an advantage over conventional wide band-type red-light-emitting phosphors. K2SiF6:Mn4+ phosphors have shown extremely narrow emission peaks in wavelengths ranging from 620 to 630 nm, leading to a higher color-rendering index and larger color gamut for the final LED applications. We examined the decay behavior in terms of radiative and non-radiative rates along with a reliable evaluation of Mn4+ concentrations. Inter-activator energy transfer played a significant role in the luminescence process in this well-known narrow peak emission type of the red phosphor K2SiF6:Mn4+.

Graphical abstract: Radiative and non-radiative decay rate of K2SiF6:Mn4+ phosphors

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Publication details

The article was received on 18 Mar 2015, accepted on 20 Apr 2015 and first published on 20 Apr 2015


Article type: Paper
DOI: 10.1039/C5TC00757G
Author version available: Download Author version (PDF)
Citation: J. Mater. Chem. C, 2015,3, 5484-5489
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    Radiative and non-radiative decay rate of K2SiF6:Mn4+ phosphors

    M. Kim, W. B. Park, B. Bang, C. H. Kim and K. Sohn, J. Mater. Chem. C, 2015, 3, 5484
    DOI: 10.1039/C5TC00757G

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