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Issue 30, 2015
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Supramolecular control of reverse spin transitions in cobalt(II) terpyridine complexes with diblock copolypeptide amphiphiles

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Abstract

Three composites composed of the cobalt terpyridine complex [CoII(MeO-terpy)2] and the diblock copolypeptide amphiphiles 1 and 2 or the polypeptide 3 (including glutamic acid and leucine) were prepared. Supramolecular structures such as rectangular morphologies were obtained from composites of 1 and 2. A perfectly reversible reverse spin transition was successfully generated in the case of composites made with 1.

Graphical abstract: Supramolecular control of reverse spin transitions in cobalt(ii) terpyridine complexes with diblock copolypeptide amphiphiles

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Publication details

The article was received on 10 Mar 2015, accepted on 24 Mar 2015 and first published on 26 Mar 2015


Article type: Communication
DOI: 10.1039/C5TC00677E
Citation: J. Mater. Chem. C, 2015,3, 7779-7783
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    Supramolecular control of reverse spin transitions in cobalt(II) terpyridine complexes with diblock copolypeptide amphiphiles

    K. Kuroiwa, T. Arie, S. Sakurai, S. Hayami and T. J. Deming, J. Mater. Chem. C, 2015, 3, 7779
    DOI: 10.1039/C5TC00677E

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