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Issue 4, 2015
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Mechanical and optical properties of ultralarge flakes of a metal–organic framework with molecular thickness

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Abstract

The isolation of 2D-materials is already a success for graphene, graphene oxide, boron nitride and a few clays or metal chalcogenides, however despite the fact that some of them show very interesting physical properties, they lack useful functionalities. Metal–Organic Frameworks (MOFs) are multifunctional materials showing a wide range of physical and chemical properties that can be structurally designed by suitable selection of their building-blocks. This strategy may allow the production of layers with a variety of useful electronic and molecular recognition functionalities. Herein we isolate 2D-MOF flakes with areas of hundreds of square microns and an excellent control of the molecular thickness (from single up to ca. 50 layers). The samples exhibit such good photoluminescence and mechanical properties as to allow free-standing characterization of few layers’ flakes.

Graphical abstract: Mechanical and optical properties of ultralarge flakes of a metal–organic framework with molecular thickness

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Publication details

The article was received on 10 Oct 2014, accepted on 16 Feb 2015 and first published on 16 Feb 2015


Article type: Edge Article
DOI: 10.1039/C4SC03115F
Citation: Chem. Sci., 2015,6, 2553-2558
  • Open access: Creative Commons BY license
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    Mechanical and optical properties of ultralarge flakes of a metal–organic framework with molecular thickness

    C. Hermosa, B. R. Horrocks, J. I. Martínez, F. Liscio, J. Gómez-Herrero and F. Zamora, Chem. Sci., 2015, 6, 2553
    DOI: 10.1039/C4SC03115F

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